The Emites used to live there,

Genesis 14:5
In the fourteenth year, Chedorlaomer and the kings allied with him went out and defeated the Rephaites in Ashteroth-karnaim, the Zuzites in Ham, the Emites in Shaveh-kiriathaim,

Joshua 13:12
the whole kingdom of Og in Bashan, who had reigned in Ashtaroth and Edrei and had remained as a remnant of the Rephaim. Moses had struck them down and dispossessed them,

Joshua 12:4
And Og king of Bashan, one of the remnant of the Rephaim, who lived in Ashtaroth and Edrei.

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a people great and many,

Deuteronomy 7:1
When the LORD your God brings you into the land that you are entering to possess, and He drives out before you many nations—the Hittites, Girgashites, Amorites, Canaanites, Perizzites, Hivites, and Jebusites, seven nations larger and stronger than you—

Deuteronomy 9:1
Hear, O Israel: Today you are about to cross the Jordan to go in and dispossess nations greater and stronger than you, with large cities fortified to the heavens.

Deuteronomy 4:38
to drive out before you nations greater and mightier than you, and to bring you into their land and give it to you for your inheritance, as it is this day.

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as tall as the Anakites.

Numbers 13:33
We even saw the Nephilim there—the descendants of Anak that come from the Nephilim! We seemed like grasshoppers in our own sight, and we must have seemed the same to them!”

Deuteronomy 1:28
Where can we go? Our brothers have made our hearts melt, saying: ‘The people are larger and taller than we are; the cities are large, with walls up to the heavens. We even saw the descendants of the Anakim there.’”

Joshua 11:21-22
At that time Joshua proceeded to eliminate the Anakim from the hill country of Hebron, Debir, and Anab, and from all the hill country of Judah and of Israel. Joshua devoted them to destruction, along with their cities. / No Anakim were left in the land of the Israelites; only in Gaza, Gath, and Ashdod did any survive.

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Numbers 13:22
They went up through the Negev and came to Hebron, where Ahiman, Sheshai, and Talmai, the descendants of Anak, dwelled. It had been built seven years before Zoan in Egypt.

Amos 2:9
Yet it was I who destroyed the Amorite before them, though his height was like that of the cedars, and he was as strong as the oaks. Yet I destroyed his fruit above and his roots below.

Numbers 21:11-13
They journeyed from Oboth and camped at Iye-abarim in the wilderness opposite Moab to the east. / From there they set out and camped in the Valley of Zered. / From there they moved on and camped on the other side of the Arnon, in the wilderness that extends into the Amorite territory. Now the Arnon is the border between the Moabites and the Amorites.

Genesis 15:18-21
On that day the LORD made a covenant with Abram, saying, “To your descendants I have given this land—from the river of Egypt to the great River Euphrates— / the land of the Kenites, Kenizzites, Kadmonites, / Hittites, Perizzites, Rephaites, …

1 Samuel 17:4-7
Then a champion named Goliath, who was from Gath, came out from the Philistine camp. He was six cubits and a span in height, / and he had a bronze helmet on his head. He wore a bronze coat of mail weighing five thousand shekels, / and he had armor of bronze on his legs and a javelin of bronze slung between his shoulders. …

2 Samuel 21:15-22
Once again the Philistines waged war against Israel, and David and his servants went down and fought against the Philistines. But David became exhausted. / Then Ishbi-benob, a descendant of Rapha, whose bronze spear weighed three hundred shekels and who was bearing a new sword, resolved to kill David. / But Abishai son of Zeruiah came to his aid, struck the Philistine, and killed him. Then David’s men swore to him, “You must never again go out with us to battle, so that the lamp of Israel may not be extinguished.” …

1 Chronicles 20:4-8
Some time later, war broke out with the Philistines at Gezer. At that time Sibbecai the Hushathite killed Sippai, a descendant of the Rephaim, and the Philistines were subdued. / Once again there was a battle with the Philistines, and Elhanan son of Jair killed Lahmi the brother of Goliath the Gittite, the shaft of whose spear was like a weaver’s beam. / And there was also a battle at Gath, where there was a man of great stature with six fingers on each hand and six toes on each foot—twenty-four in all. He too was descended from Rapha, …